It turned out that they could! #ElementTales started with mendelevium, and meandered — avoiding a few forks — all the way to gadolinium. Some of the links are funny, some are tenuous, and a lot refer to fascinating bits of chemistry trivia.
It seemed a shame not to preserve the final thread somehow. Each of the entries below is headed with a link to the original tweet — just in case you’d like to find, and follow, the thread yourself.
@allisontau Zinc is element 30. Zinc rhymes with sink. If your kitchen sink is broken you call a plumber. Plumbers are called plumbers after plumbum, the Latin word for the element lead (Pb), because the Romans used lead to make pipes.
@Mark_Lorch Lead in Greek is μολυβδος – Molyvdos which gives use the name of element 42, molybdenum.
@chronicleflask Molybdenum-containing enzymes are found in bacteria: the simplest and oldest of the living organisms. Living organisms on planet Earth have carbon-based biology. (Time for some non-metals, I thought!)
This could be taken in so many directions based on carbon‘s chemistry, but I’ll ruin it — carbon reminds me of “Carboniferous”, which sounds like it should have something to do with iron (it doesn’t).
@sciencenotscary Iron is in the same column of the periodic table as ruthenium, which usually means it should have similar reactivity and chemical behaviour, but it turns out iron is actually completely useless as a catalyst and will not get you a PhD.
I’ve had a couple of people mistake my cat’s name, RuPhos, for something to do with ruthenium – it really isn’t, it’s a phosphorus ligand.
@Mark_Lorch Phosphorus was first extracted from urine by Hennig Brandt in 1669. Later is was discovered that bone is calcium phosphate, which made for a ready supply to feed the match industry.
@David_S_Bristol Calcium and phosphorous combine in bone along with a substantial amount of magnesium. ~60% of magnesium in the body is in bone. It is essential for a healthy skeleton and reduced magnesium is linked to osteoporosis.
@Stare_at_Air Magnesium is a key component of Grignard reagents. Grignard shared his Nobel Prize with Sabatier, who in turn received it for his method of hydrogenating organic compounds. Hydrogen.
@drdelusional Hydrogen, the lightest element, forms the majority of the mass of the Universe. This odorless and tasteless gas combines with Fluorine to result in hydrogen fluoride, a highly reactive acid.
(Side note: corrosive, not (especially) reactive.)
Electronegativity generally increases from left to right across a period, and generally decreases from top to bottom. Fluorine is the most electronegative element on the Pauling electronegativity scale. The LEAST electronegative element is (probably) caesium.
Ooh, ooh: Robert Bunsen (he of the burner) and Gustav Kirchhoff discovered two alkali metals, cesium and rubidium, in 1860.
@Stare_at_Air Rubidium is one of several elements named after a colour (in this case the red lines seen in the emission spectrum), but chromium is associated with so many different colours it’s just named after the Greek word for colour, χρῶμα.
Amongst the Terracotta warriors were found what appears to be chrome (chromium) plated bronze swords. The alloy was mostly copper and tin, but also contained magnesium, nickel and cobalt.
@sumants Cobalt is named from ‘kobold’, German for ‘goblin’. This comes from German miners – who were harvesting (cobalt) blue pigments – naming ores ‘goblin ores’ due to the effects of arsenic poisoning when the ores were smelted.
The use of Scheele’s Green, a popular green arsenic-based pigment, caused poisonings in the 19th century from its use in wallpaper, candles, even food. Similarly, in the 1920s, the “Radium Girls” developed cancer from painting watch faces with radium-based pigment.
@Mark_Lorch Radium was discovered by Marie and Pierre Curie when they extracted it from Uraninite ore. From the same ore they extracted another element which they initially called radium-F. Later Marie renamed if after her home country – Poland. Giving us … Polonium.
I think the f-block is feeling a bit unloved, so let’s go from the elements that the Curies discovered (Polonium) to the one named after them. Curium.
@Stare_at_Air Plutonium was indirectly named by a child (the name Pluto for the planet was suggested by an 11-year-old girl). The only other element named by a child is neon, suggested by Ramsay’s son.
William Ramsay (neon) was also the first person to isolate helium. Prior to this is was known to exist from the spectra of the Sun. Hence the element’s name from Helios… Helium.
Inhaling helium makes your voice squeaky. What happens if you inhale xenon? Researchers at a prestigious US lab decided to find out. Turns out, “heavier than air”=”too heavy for lungs to expel”. The experimenter’s life was saved when he stood on his head.
(Side note: watch what happened when Dr Bunhead of Brainiac tried the same thing.)
@FioraAeterna Xenon is a really unusual element. In fact, it’s the only pure element that is also a general anesthetic! Yet it’s an unreactive noble gas. Weird, huh? For weird reasons, both Xenon and Argon are now on the anti-doping banned chemicals list.
People are often surprised to find that the third most abundant gas in the Earth’s atmosphere is Argon. Perhaps similarly surprising is that the third most abundant element in the universe as a whole (at least as far as we know) is oxygen.
@sumants Neodymium was originally mined as a twinned material known as didymium. Carl Auer von Welsbach fractionally distilled didymium to isolate neodymium (new twin) and the other “green twin”, praesodymium.
“Green twin” in Greek (πράσινος and δίδυμος) is the base for the name of praseodymium — meanwhile “green twig” in Greek (θαλλός) is the base for the name of thallium, after the bright green spectral line used to identify it.
A little while back now I was researching my post on water when I came across a scientist which I hadn’t heard of before. And that was odd, because this person was one of the first to propose the idea of catalysis, which is a pretty important concept in chemistry, in fact, in science in general. Surely the name should be at least a bit familiar. Shouldn’t it?
And yet it wasn’t, and the more I read, the more surprised I was. Not only was this person clearly a brilliant thinker, they were also remarkably prescient.
Elizabeth Fulhame’s book was first published in 1794 (image by the Science History Institute, Public Domain)
So who was it? Her name was Elizabeth Fulhame, and we know very little about her, all things considered. Look her up and you won’t find any portraits, or even her exact dates of birth and death, despite the fact that her book, An Essay on
Combustion, was published in more than one country and she, a Scottish woman, was made an honorary member of the Philadelphia Chemical Society in 1810 — remarkable achievements for the time.
As well as describing catalytic reactions for the first time, that book — first published in 1794 and surprisingly still available today — also contains a preface which includes the following:
But censure is perhaps inevitable; for some are so ignorant,
that they grow sullen and silent, and are chilled with horror
at the sight of any thing, that bears the semblance of learning,
in whatever shape it may appear; and should the spectre
appear in the shape of a woman, the pangs, which they suffer,
are truly dismal.
Obviously women are interested in physics. And also, apparently, in staring wistfully into open vacuum chambers whilst wearing unnecessary PPE (stock photos are great, aren’t they?)
Fulhame clearly did not suffer fools gladly (I think I would’ve liked her), and had also run across a number of people who felt that women were not capable of studying the sciences.
Tragically, 225 years later, this attitude still has not entirely gone away. Witness, for example, the recent article featuring an interview with Alessandro Strumia, in which he claimed that women simply don’t like physics. There were naturally a number of excellent rebuttals to this ludicrous claim, not least a brilliant annotated version of the article by Shannon Palus — which I recommend because, firstly, not behind a paywall and secondly, very funny.
Unfortunately, despite the acclaim she received at the time, Fulhame was later largely forgotten. One scientist who often gets the credit for “discovering” catalysis is Berzelius. There is no doubt that he was a remarkable chemist (you have him to thank for chemical notation, for starters), but he was a mere 15 years old when Fulhame published her book.
The RSC’s Breaking the Barriers report was published in 2018
She pointed out that today there is an almost an equal gender split in students studying chemistry at undergraduate level in the United Kingdom, but admitted that there is still much to be done, saying:
“The two recent RSC reports ‘Diversity Landscape of the Chemical Sciences’ and ‘Breaking the Barriers’ have highlighted some of the key issues. Although nearly 50% of undergraduate students studying to become chemists are female, the numbers reaching positions of seniority are considerably less.”
Professor Resmini was keen to stress that there are many supportive men in academia, and that’s something we mustn’t forget. Indeed, this was true even in Fulhame’s time. Thomas P. Smith, a member of the Philadelphia Chemical Society’s organizing committee, applauded her work, saying “Mrs. Fulham has now laid such bold claims to chemistry that we can no longer deny the sex the privilege of participating in this science also.” Which may sound patronising to 21st century ears, but it was 1810 after all. Women wouldn’t even be trusted to vote for another century, let alone do tricky science.
I think I’ve found Strumia’s limousine; it’s bright red, very loud, and can only manage short distances.
Speaking of patronising comments, another thing that Strumia said in his interview was, “It is not as if they send limousines to pick up boys wanting to study physics and build walls to keep out the women.”
This is one of those statements that manages, at the same time, to be both true and also utterly absurd. Pupils, undergraduates, post-grads and post-docs do not exist in some sort of magical vacuum until, one day, they are presented with a Grand Choice to continue, or not, with their scientific career. Their decision to stop, if it comes, is influenced by a thousand, often tiny, things. Constant, subtle, nudges which oh-so-gently push them towards, or away, and which start in the earliest years of childhood. You only need to spend five minutes watching the adverts on children’s television to see that girls and boys are expected to have very different interests.
Textbooks may be studied by girls, but they rarely mention the work of female scientists.
So let’s end with another of Professor Resmini’s comments: that the work of past female scientists deserves greater recognition than it has received. This could not be more true, and this lack of representation is exactly one of those nudges I mentioned. Pick up a chemistry textbook and look for the pictures of female scientists: there might be a photo of Marie Curie, if you’re lucky. Kathleen Lonsdale usually gets a mention in the section on benzene in post-GCSE texts. But all too often, that’s about it. On the other hand, pictures of Haber, J. J. Thompson, Rutherford, Avogadro and Mendeleev are common enough that most chemistry students could pick them out of a lineup.
We should ask ourselves about the message this quietly suggests: that women simply haven’t done any “serious” chemistry (this is not the case, of course) and… perhaps never will?
Ruthenium is rare transition metal belonging to the platinum group of elements
What shall I write about this week, I wonder… how about, apropos of nothing, the element ruthenium? It is the International Year of the Periodic Table after all; there have to be some element-themed posts, right?
You might remember from school (or possibly from your jewellery) that platinum is really unreactive. What has this got to do with ruthenium? Well, unreactive metals can be found in nature as actual metal, rather than combined with other elements in ores. But it turns out that early “platinum metal” — used by pre-Columbian Americans — wasn’t pure, but was in fact an alloy of platinum with other metals.
Gottfried Osann discovered ruthenium before Klaus, but gave up his claim.
In 1827 Jöns Berzelius and Gottfried Osann dissolved crude platinum from the Ural Mountains in aqua regia: a 1:3 mixture of nitric acid and hydrochloric acid (we’ve met aqua regia before, in a famous story about Nobel Prize medals). Osann was certain that he’d isolated three new metals, which he named pluranium, ruthenium, and polinium, but Berzelius disagreed, and this caused a long-running dispute between the two scientists.
Osann eventually gave up the argument — which was a shame, because he was right. In 1844 Karl Ernst Klaus analysed the compounds prepared by Osann and showed that they did, in fact, contain ruthenium.
Klaus had been studying the insoluble residues left over after platinum extraction from Ural placer deposits. Like many chemists at the time, he tasted and smelled the substances he prepared, and he reported that the ammines of ruthenium had a more caustic taste than alkalis, while the taste of osmium tetroxide was “acute pepper-like” (do not try this at home).
He communicated his discoveries to the Academy of Sciences at St. Petersburg and to Academician G. I. Gess, who reported them on September 13th and October 25th, 1844. Klaus named the new element from the Latin word, Ruthenia, and mentioned Osann’s work, saying:
“I named the new body, in honour of my Motherland, ruthenium. I had every right to call it by this name because Mr. Osann relinquished his ruthenium and the word does not yet exist in chemistry”
ruthenium chloride is sometimes shown as red, but it’s actually black
Klaus died of pneumonia in 1864, and the study of ruthenium in Russia more or less stopped for the best part of seventy years, not restarting until the 1930s. The element is now known to harden platinum and palladium alloys, and is used in electrical contacts as a result. When just 0.1% is added to titanium it forms an extremely corrosion-resistant alloy which is particularly useful in seawater environments.
Ruthenium and its compounds have lots of other uses, too, including cancer treatments and in catalysis. Ruthenium(VIII) oxide, a colourless liquid (just: its melting point is 25 oC) forms brown-black ruthenium dioxide in contact with fatty oils; because of this property it’s used in forensics to expose latent fingerprints.
This Swarovski necklace has been plated with ruthenium
One of the most vibrant ruthenium compounds is the dye, “ruthenium red”, which has been used as a biological stain for over 100 years. It has the complicated formula [Ru3O2(NH3)14]Cl6 and is made by reacting ruthenium trichloride with ammonia in air, which might explain why pictures of ruthenium trichloride sometimes show a red substance, when it’s actually a rather boring black.
One place where you might have come across ruthenium in everyday life is jewellery: the metal’s hardness, high corrosion resistance and unusual, not-quite-metallic grey-black finish make it popular choice. Pure ruthenium is expensive though, so it’s almost always plated onto a cheaper base metal.
And now, one last picture to mark my ruthenium-day: check out my fabulous chemistry-themed birthday cake (thanks, Mum!), made by the Cotswold Cake Room. How amazing is this?
Normally at the end of my blog posts I link to my ko-fi account, but this time, instead, if you’re feeling generous please consider donating to my birthday fundraiser to raise money for Alzheimer’s Research UK.
The fundraiser is running through Facebook, which I appreciate doesn’t suit everyone — if you’d like to donate without going via that particular social network, there’s a link to donate directly here. Do drop me a comment below if you do, so that I can say thank you x
Skipping over a few centuries of pursuing what was, we know now, a bit of a dead-end in terms of the whole earth, air, fire and water thing, in 1661, Robert Boyle was probably the first to state that elements were the building blocks of matter and were irreducible but, and this was the crucial bit, that we didn’t know what all the elements were, or even how many there might be.
Antoine Lavoisier wrote one of the first lists of chemical elements.
Things moved on pretty quickly after that. Just thirty years later, Jöns Jakob Berzelius had worked out the atomic weights for 45 of the 49 elements that were known at that point.
So it was that by the 1810s, chemists knew of 50 or so chemical elements, and had atomic weights for most of them. It was becoming clear that more elements were going to turn up, and the big question became: how do we organise this ever-increasing list? It was a tricky problem. Imagine trying to put together a jigsaw puzzle where two-thirds of the pieces are missing, there’s no picture on the box, and a few pieces have been tossed in from other puzzles for good measure.
Enter Johann Döbereiner, who in 1817 noticed that there were patterns in certain groups of elements, which he called triads. For example, he spotted that lithium, sodium and potassium behaved in similar ways, and realised that if you worked out the average atomic mass of lithium and potassium, you got a value that was close to that of sodium’s. At the time he could only find a few triads like this, but it was enough to suggest that there must be some sort of structure underlying the list of elements.
In 1826 Jean-Baptiste Dumas (why do all these chemists have first names starting with J?) perfected a method for measuring vapour densities, and worked out new atomic mass values for 30 elements. He also set the value for hydrogen at 1, in other words, placing hydrogen as the “first” element.
Newland’s table of the elements had “periods” going down and “groups” going across, but otherwise looks quite familiar.
Next up was John Newlands (another J!), who published his “Law of Octaves” in 1865. Arranging the elements in order of atomic mass, he noticed that properties seemed to be repeating in groups of eight. His rows and columns were reversed compared to what we use today — he had groups going across, and periods going down — but apart from that the arrangement he ended up with is decidedly familiar. Other chemists, though, didn’t appreciate the musical reference, and didn’t take Newlands very seriously.
Which brings us, finally, to Dmitri Mendeleev (various other spellings of his name exist, including Dmitry Mendeleyev, but Dmitri Mendeleev seems to be the most accepted one). His early life history is a movie-worthy story (I won’t go into that else we’ll be here all day, but check it out, it’s really quite amazing). When he was just 35 he made a formal presentation to the Russian Chemical Society, titled The Dependence between the Properties of the Atomic Weights of the Elements, which made a number of important points. He noted, as Newlands had already suggested, that there were repeating patterns in the elements, or periodicity, and that there did indeed seem to be connections between sequences of atomic weights and chemical properties.
Dmitri Mendeleev suggested there were many elements yet to be discovered.
Most famously, Mendeleev suggested that there were many elements yet to be discovered, and he even went so far as to predict the properties of some of them. For example, he said there would be an element with similar properties to silicon with an atomic weight of 70, which he called ekasilicon. The element was duly discovered, in 1886 by Clemens Winkler, and named germanium, in honor of Germany: Winkler’s homeland. Germanium turns out to have an atomic mass of 72.6.
Mendeleev also predicted the existence of gallium, which he named ekaaluminium, and predicted, amongst other things, that it would have an atomic weight of 68 and a density of 5.9 g/cm3. When the element was duly discovered by the French chemist Paul Emile Lecoq de Boisbaudran, he first determined its density to be 4.7 g/cm3. Mendeleev was so sure of his prediction that he wrote to Lecoq and told him to check again. It turned out that Mendeleev was right: gallium’s density is actually 5.9 g/cm3 (and its atomic weight is 69.7).
Despite constructing the one thing that every chemist over the last 150 years has spent years of their life poring over, Mendeleev was never awarded the Nobel Prize for Chemistry. He was nominated in 1906, but the story goes that Svante Arrhenius — who had a lot of influence in the Royal Swedish Academy of Sciences — held a grudge against Mendeleev because he’d been critical of Arrhenius’s dissociation theory, and argued that the periodic system had been around for far too long by 1906 to be recognised for the prize. Instead, the Academy awarded the Nobel to Henri Moissan, for his work on isolating fluorine from its compounds (no doubt impressive, not to mention dangerous, chemistry).
Henry Moseley proposed that atomic number was equal to the number of protons in the nucleus of an atom.
Mendeleev died in 1907 at the age of 72, just before the discovery of the proton and Henry Moseley’s work, in 1913, which proposed that the atomic numbers of elements should be equal to the number of positive charges (protons) they contained in their nuclei. This discovery would have pleased Mendeleev, who had already suggested, based on their properties, that some elements shouldn’t be placed in the periodic table strictly in order of atomic weight.
As has become traditional, I’m finishing off this year with a round-up of 2018’s posts. It’s been a good year: a few health scares which turned out to be nothing much to worry about, one which turned out to be a genuine danger, a couple of cool experiments and some spectacular shiny balls. So without further ado, here we go…
February featured BPA: an additive in many plastics.
In February I wrote a piece about BPA (Bisphenol A), which was the chemical scare of the day. There’s always one around January/February time. It’s our penance for daring to enjoy Christmas. Anyway, BPA is a chemical in many plastics, and of course plastic waste had become – and remains – a hot topic. BPA is also used in a number of other things, not least the heat sensitive paper used to produce some shopping receipts. It’s not a harmless substance by any means, but it won’t surprise anyone to learn that the risks had, as is usually the case, been massively overstated. In a report, the European Food Safety Authority said that the health concern for BPA is low at their estimated levels of exposure. In other words, unless you’re actually working with it – in which case you should have received safety training – there’s no need to be concerned.
In March I recorded an episode for the A Dash of Science podcast, and I went on to write a post about VARD, which stands for Verify, Author, Reasonableness and Date. It’s my quick and easy way of fact-checking online information – an increasingly important skill these days. Check out the post for more info.
April ended up being all about dairy and vitamin D.
April was all about dairy after a flare-up on Twitter on the topic, and went on to talk about vitamin D. The bottom line is that everyone in the UK should be taking a small vitamin D supplement between about October and March, because northern Europeans simply can’t make vitamin D3 in their skin during these months (well, unless they travel nearer to the equator), and it’s not a nutrient we can easily get from our food. Are you taking yours?
Mayfeatured fish tanks, following a widely reported story about a fish-owner who cleaned out his tank and managed to release a deadly toxin that poisoned his entire family. Whoops. It turns that this was, and is, a real risk – so if you keep fish and you’ve never heard of this before, do have a read!
Slime turned up again in July. And December. And will probably keep on rearing its slimy head.
July brought a subject which has turned up again recently: slime. I wrote about slime in 2017, too. It’s the gift that keeps on giving. This time it flared up because the consumer magazine and organisation Which? kept promoting research that, they claimed, showed that slime toys contain dangerous levels of borax. It’s all rather questionable, since it’s not really clear which safety guidelines they’re applying and whether they’re appropriate for slime toys. Plus, the limits that I was able to find are migration limits. In other words, it’s not appropriate to measure the total borax content of the slime and declare it dangerous – they should be looking at the amount of borax which is absorbed during normal use. Unless your child is eating slime (don’t let them do that), they’re never going to absorb enough borax to do them any harm. In other words, it’s a storm in a slimepot.
August was all about carbon dioxide, after a heatwave spread across Europe and there was, bizarrely, a carbon dioxide shortage which had an impact on all sorts of things from fizzy drinks to online shopping deliveries. It ended up being a long-ish post which spanned everything from the formation of the Earth, the discovery of carbon dioxide, fertilisers and environmental concerns.
September featured shiny, silver balls.
In September I turned my attention to a chemical reaction which is still to this day used to coat the inside of glass decorations with a thin layer of reflective silver, and has connections with biochemistry, physics and astronomy. Check it out for some pretty pictures of silver balls, and my silver nitrate-stained fingers.
In October I was lucky enough to go on a ‘fungi forage’ and so, naturally, I ended up writing all about mushrooms. Did you know that a certain type of mushroom can be used to make writing ink? Or that some mushrooms change colour when they’re damaged? No? You should go back and read that post, then! (And going back to April for a moment, certain mushrooms are one of the few sources of vitamin D.)
Finally, November ended up being all about water, marking the 235th anniversary of the day that Antoine Lavoisier formally declared water to be a compound. It went into the history of water, how it was proven to have the formula H2O, and I even did an experiment to split water into hydrogen and oxygen in my kitchen – did you know that was possible? It is!
As December neared, the research for my water piece led me to suggest to Andy Brunning of Compound Interest that this year’s Chemistry Advent might feature scientists from the last 24 decades of chemistry, starting in the 1780s (with Lavoisier and Paulze) and moving forward to the current day. This turned out to be a fantastic project, featuring lots of familiar and not quite so-familiar scientists. Do have a look if you didn’t follow along during December.
And that’s it for this year. I hope it’s been a good one for all my readers, and I wish you peace and prosperity in 2019! Suggestions for the traditional January Health Scare, anyone? (Let’s hope it’s not slime again, I’m getting really tired of that one now…)
235 years seems like an awfully long time, probably so long ago that no one knew anything very much. Practically still eye of newt, tongue of bat and leeches for everyone, right? Well, not quite. In fact, there was some nifty science and engineering going on at the time. It was the year that Jean-François Pilâtre de Rozier and François Laurent made the first untethered hot air balloon flight, for example. And chemistry was moving on swiftly: lots of elements had been isolated, including oxygen (1771, by Carl Wilhelm Scheele) and hydrogen (officially by Henry Cavendish in 1766, although others had observed it before he did).
Cavendish had reported that hydrogen produced water when it reacted with oxygen (known then as inflammable air and dephlogisticated air, respectively), and others had carried out similar experiments. However, at the time most chemists favoured phlogiston theory (hence the names) and tried to interpret and explain their results accordingly. Phlogiston theory was the idea that anything which burned contained a fire-like element called phlogiston, which was then “lost” when the substance burned and became “dephlogisticated”.
Cavendish, in particular, explained the fact that inflammable air (hydrogen) left droplets of “dew” behind when it burned in “common air” (the stuff in the room) in terms of phlogiston, by suggesting that water was present in each of the two airs before ignition.
Antoine-Laurent Lavoisier proved that water was a compound. (Line engraving by Louis Jean Desire Delaistre, after a design by Julien Leopold Boilly.)
Lavoisier was very much against phlogiston theory. He carried out experiments in closed vessels with enormous precision, going to great lengths to prove that many substances actually became heavier when they burned and not, as phlogiston theory would have it, lighter. In fact, it’s Lavoisier we have to thank for the names “hydrogen” and “oxygen”. Hydrogen is Greek for “water-former”, whilst oxygen means “acid former”.
When, in June 1783, Lavoisier found out about Cavendish’s experiment he immediately reacted oxygen with hydrogen to produce “water in a very pure state” and prove that the mass of the water which formed was equal to the combined masses of the hydrogen and oxygen he started with.
He then went on to decompose water into oxygen and hydrogen by heating a mixture of water and iron filings. The oxygen that formed combined with the iron to form iron oxide, and he collected the hydrogen gas over mercury. Thanks to his careful measurements, Lavoisier was able to demonstrate that the increased mass of the iron filings plus the mass of the collected gas was, again, equal to the mass of the water he had started with.
Water is a compound of hydrogen and oxygen, with the formula H2O.
There were still arguments, of course (there always are), but phlogiston theory was essentially doomed. Water was a compound, made of two elements, and the process of combustion was nothing more mysterious than elements combining in different ways.
As an aside, Scottish chemist Elizabeth Fulhame deserves a mention at this point. Just a few years after Lavoisier she went on to demonstrate through experiment that many oxidation reactions occur only in the presence of water, but the water is regenerated at the end of the reaction. She is credited today as the chemist who invented the concept of catalysis. (Which is a pretty important concept in chemistry, and yet her name never seems to come up…)
Anyway, proving water’s composition becomes a lot simpler when you have a ready supply of electricity. The first scientist to formally demonstrate this was William Nicholson, in 1800. He discovered that when leads from a battery are placed in water, the water breaks up to form hydrogen and oxygen bubbles, which can be collected separately at the submerged ends of the wires. This is the process we now know as electrolysis.
You can easily carry out the electrolysis of water at home.
In fact, this is a really easy (and safe, I promise!) experiment to do yourself, at home. I did it myself, using an empty TicTac box, two drawing pins, a 9V battery and a bit of baking soda (sodium hydrogencarbonate) dissolved in water – you need this because water on its own is a poor conductor.
The drawing pins are pushed through the bottom of the plastic box, the box is filled with the solution, and then it’s balanced on the terminals of the battery. I’ve used some small test tubes here to collect the gases, but you’ll be able to see the bubbles without them.
Bubbles start to appear immediately. I left mine for about an hour and a half, at which point the test tube on the negative terminal (the cathode) was completely full of gas, which produced a very satisfying squeaky pop when I placed it over a flame.
The positive electrode (the anode) ended up completely covered in what I’m pretty sure is a precipitate of iron hydroxide (the drawing pins presumably being plated steel), which meant that very little oxygen was produced after the first couple of minutes. This is why in proper electrolysis experiments inert graphite or, even better, platinum, electrodes are used. If you do that, you’ll get a 1:2 ratio by volume of oxygen to hydrogen, thus proving water’s formula (H2O) as well.
So there we have it: water is a compound, and not an element. And if you’d like to amuse everyone around the Christmas dinner table, you can prove it with a 9V battery and some drawing pins. Just don’t nick the battery out of your little brother’s favourite toy, okay? (Or, if you do, don’t tell him it was my idea.)
Glistening ink caps produce a dark, inky substance.
Yesterday I had the fantastic experience of a “fungi forage” with Dave Winnard from Discover the Wild, organised by Incredible Edible Oxford. There are few nicer things than wandering around beautiful Oxfordshire park- and woodland on a sunny October day, but Dave is also an incredibly knowledgeable guide. I’ve always thought mushrooms and fungi were interesting – living organisms that are neither plants nor animals and which we rely on for everything from antibiotics to soy sauce – but I had lots to learn.
And from a practical point of view, what about the fact that people once used certain fungi to light fires? I’ve always imagined fungi as being quite wet things with a high water content (unless they’re deliberately dried, of course), but some are naturally very dry. Ötzi, the mummified man thought to have lived between 3400and 3100 BCE, was found with two types of fungus on him: birch fungus, which has antiparasitic properties, and a type of tinder fungus which can be ignited with a single spark and will smolder for days.
Coprine causes unpleasant symptoms, including nausea and vomiting, when consumed with alcohol.
Then, of course, there’s all the interesting chemistry. Early on in the day, we came across some glistening ink caps.The gills of these disintegrate to produce a black, inky liquid which contains a form of melanin and can be used as ink. And there’s more to this story: as I’ve already mentioned, fungi are not plants and they can’t photosynthesise, but it seems that some fungi do use melanin to harness gamma rays as energy for growth. Extra mushrooms for the Hulk’s breakfast, then?
Moving away from pigments for a moment, a related species to the glistening ink cap, the common ink cap, contains a chemical called coprine. This causes lots of unpleasant symptoms if it’s consumed with alcohol, similar to Disulfiram, the drug used to treat alcoholism. For this reason one of this mushroom’s other names is tippler’s bane. The coprine in the mushrooms effectively causes an instant hangover by accelerating the formation of acetaldehyde (also known as ethanal) from alcohol. Definitely don’t pair that mushroom omelette with a nice bottle of red and, worse, you’ll need to stay off the booze for a while: apparently the effects can linger for a full three days.
Yellow stainer mushrooms look like field mushrooms, but are poisonous.
The real giveaway with yellow stainers, though, is their tendency to turn yellow when bruised or scratched, hence the name. This, it seems, is due to 4,4′-dimethoxyazobenzene. The name might not be familiar, but A-level Chemistry students will recognise the structure: it’s an azo-dye. Quite apart from being a very useful word in Scrabble, azo compounds are well-known for their characteristic orange/yellow colours. It’s not really clear whether it forms in the mushroom due to some sort of oxidation reaction, or whether it’s in the cells anyway but only becomes visible when the cells are damaged. Either way, it’s something to look out for if you spot a patch of what look like field mushrooms.
The blushing wood mushroom.
We also came across several species which are safe to eat. One I might look out for in future is the blushing wood mushroom. As is often the way with fungi, the name is literal rather than merely poetic. These mushrooms have a light brown cap, beige gills, and a pale stem, but they turn bright red when cut or scratched due to the formation of an ortho-quinone. It’s quite a dramatic colour-change, and makes them pretty easy to identify. Apparently they’re normally uncommon here, but we found quite a lot of them, which might be something to do with this year’s unusally hot and dry summer.
Red ortho-quinone causes blushing wood mushrooms to literally blush.
I tried to find out the reasons for these colour-changes. In the plant and animal kingdoms pigments are usually there for good reason: camouflage, signalling and communication or, as with chlorophyll, as a way of making other substances. Fruits, for example, often turn bright red as they ripen because it makes them stand out from the green foilage and encourages animals to eat them so that the seeds can be spread. Likewise, they’re green when they’re unripe because it makes them less obvious and less appealing. But what’s the advantage for the mushroom to change colour once it’s already damaged? Perhaps there isn’t one, and it’s just an accident of their biology, but if so it seems strange that it’s a feature of several species. I couldn’t find the answer; if any mycologists are reading this and know, get in touch!
Velvet shank mushrooms.
Other edible species we met were fairy ring champignons, field blewits and jelly ear fungus – which literally looks like a sort of transparent ear. I’ll definitely be looking out for all of these in the future, but it’s important to watch out for dangerous lookalikes. Funeral bell mushrooms, for example, look like the velvet shank mushrooms we found but, once again, the name is quite literal – funeral bells contain amatoxins and eating them can cause kidney and liver failure. As Dave was keen to remind us: never eat anything you can’t confidently name!
A new school term has started here, and for me this year that’s meant more chemistry experiments – hurrah!
Okay, actually round-bottomed flasks
The other day it was time for the famous Tollens’ reaction. For those that don’t know, this involves a mixture of silver nitrate, sodium hydroxide and ammonia (which has to be freshly made every time as it doesn’t keep). Combine this concoction with an aldehyde in a glass container and warm it up a bit and it forms a beautiful silver layer on the glass. Check out my lovely silver balls!
This reaction is handy for chemists because the silver mirror only appears with aldehydes and not with other, similar molecules (such as ketones). It works because aldehydes are readily oxidised or, looking at it the other way round, the silver ions (Ag+) are readily reduced by the aldehyde to form silver metal (Ag) – check out this Compound Interest graphic for a bit more detail.
But this is not just the story of an interesting little experiment for chemists. No, this is a story of chemistry, biochemistry, physics, astronomy, and artisan glass bauble producers. Ready? Let’s get started!
Bernhard Tollens (click for link to image source)
The reaction is named after Bernhard Tollens, a German chemist who was born in the mid-19th century. It’s one of those odd situations where everyone – well, everyone who’s studied A level Chemistry anyway – knows the name, but hardly anyone seems to have any idea who the person was.
Tollens went to school in Hamburg, Germany, and his science teacher was Karl Möbius. No, not the Möbius strip inventor (that was August Möbius): Karl Möbius was a zoologist and a pioneer in the field of ecology. He must have inspired the young Tollens to pursue a scientific career, because after he graduated Tollens first completed an apprenticeship at a pharmacy before going on to study chemistry at Friedrich Wöhler’s laboratory in Göttingen. If Wöhler’s name seems familiar it’s because he was the co-discoverer of beryllium and silicon – without which the electronics I’m using to write this article probably wouldn’t exist.
After he obtained his PhD Tollens worked at a bronze factory, but it wasn’t long before he left to begin working with none other than Emil Erlenmeyer – yes, he of the Erlenmeyer flask, otherwise known as… the conical flask. (I’ve finally managed to get around to mentioning the piece of glassware from which this blog takes its name!)
It seems though that Tollens had itchy feet, as he didn’t stay with Erlenmeyer for long, either. He worked in Paris and Portugal before eventually returning to Göttingen in 1872 to work on carbohydrates, going on to discover the structures of several sugars.
Table sugar is sucrose, which doesn’t produce a silver mirror with Tollens’ reagent
All of the monosaccharides will produce a positive result with Tollens’ reagent (even when their structures don’t appear to contain an aldehyde group – this gets a bit complicated but check out this link if you’re interested). However, sucrose does not. Which means that Tollens’ reagent is quick and easy test that can be used to distinguish between glucose and sucrose.
Laboratory Dewar flask with silver mirror surface
And it’s not just useful for identifying sugars. Tollens’ reagent, or a variant of it, can also be used to create a high-quality mirror surface. Until the 1900s, if you wanted to make a mirror you had to apply a thin foil of an alloy – called “tain” – to the back of a piece of glass. It’s difficult to get a really good finish with this method, especially if you’re trying to create a mirror on anything other than a perfectly flat surface. If you wanted a mirrored flask, say to reduce heat radiation, this was tricky. Plus it required quite a lot of silver, which was expensive and made the finished item quite heavy.
Which was why the GermanchemistJustus von Liebig (yep, the one behind the Liebig condenser) developed a process for depositing a thin layer of pure silver on glass in 1835. After some tweaking and refining this was perfected into a method which bears a lot of resemblance to the Tollens’ reaction: a diamminesilver(I) solution is mixed with glucose and sprayed onto the surface of the glass, where the silver ions are reduced to elemental silver. This process ticked a lot of boxes: not only did it produce a high-quality finish, but it also used such a tiny quantity of silver that it was really cheap.
And it turned out to be useful for more than just laboratory glassware. The German astronomer Carl August von Steinheil and French doctor Leon Foucault soon began to use it to make telescope mirrors: for the first time astronomers had cheap, lightweight mirrors that reflected far more light than their old mirrors had ever done.
These days, silvering is done by vacuum deposition, which produces an even more perfect surface, but you just can’t beat the magic of watching the inside of a test tube or a flask turning into a beautiful, shiny mirror.
Speaking of which, according to @MaChemGuy on Twitter, this is the perfect, foolproof, silver mirror method:
° Place 5 cm³ 0.1 mol dm⁻³ AgNO₃(aq) in a test tube.
° Add concentrated NH₃ dropwise untill the precipitate dissolves. (About 3 drops.)
° Add a spatula of glucose and dissolve.
° Plunge test-tube into freshly boiled water.
Silver nitrate stains the skin – wear gloves!
One word of warning: be careful with the silver nitrate and wear gloves. Else, like me, you might end up with brown stains on your hands that are still there three days later…
Carbon dioxide is a small molecule with the structure O=C=O
Carbon dioxide has been in and out of the news this summer for one reason or another, but why? Is this stuff helpful, or heinous?
It’s certainly a significant part of our history. Let’s take that history to its literal limits and start at the very beginning. To quote the great Terry Pratchett: “In the beginning, there was nothing, which exploded.”
(Probably.) This happened around 13.8 billion years ago. Afterwards, stuff flew around for a while (forgive me, cosmologists). Then, about 4.5 billion years ago, the Earth formed out of debris that had collected around our Sun. Temperatures on this early Earth were extremely hot, there was a lot of volcanic activity, and there might have been some liquid water. The atmosphere was mostly hydrogen and helium.
The early Earth was bashed about by other space stuff, and one big collision almost certainly resulted in the formation of the Moon. A lot of other debris vaporised on impact releasing gases, and substances trapped within the Earth started to escape from its crust. The result was Earth’s so-called second atmosphere.
An artist’s concept of the early Earth. Image credit: NASA. (Click image for more.)
The point being that carbon dioxide is not a new phenomenon. It is, in fact, the very definition of an old phenomenon. It’s been around, well, pretty much forever. And so has the greenhouse effect. The early Earth was hot. Really hot. Possibly 200 oC or so, because these atmospheric gases trapped the Sun’s heat. Over time, lots and lots of time, the carbon dioxide levels reduced as it became trapped in carbonate rocks, dissolved in the oceans and was utilised by lifeforms for photosynthesis.
Fast-forward a few billion years to the beginning of the twentieth century and atmospheric carbon dioxide levels were about 300 ppm (0.03%), tiny compared to oxygen (about 20%) and nitrogen (about 78%).
Chemists and carbon dioxide
Flemish chemist Jan Baptist van Helmont discovered that if he burned charcoal in a closed vessel, the mass of the resulting ash was much less than that of the original charcoal.
Let’s pause there for a moment and have a little look at some human endeavours. In about 1640 Flemish chemist Jan Baptist van Helmont discovered that if he burned charcoal in a closed vessel, the mass of the resulting ash was much less than that of the original charcoal. He had no way of knowing, then, that he had formed and collected carbon dioxide gas, but he speculated that some of the charcoal had been transmuted into spiritus sylvestris, or “wild spirit”.
In 1754 Scottish chemist Joseph Black noticed that heating calcium carbonate, aka limestone, produced a gas which was heavier than air and which could “not sustain fire or animal life”. He called it “fixed air”, and he’s often credited with carbon dioxide’s discovery, although arguably van Helmont got there first. Black was also the first person to come up with the “limewater test“, where carbon dioxide is bubbled through a solution of calcium hydroxide. He used the test to demonstrate that carbon dioxide was produced by respiration, an experiment still carried out in schools more than 250 years later to show that the air we breathe out contains more carbon dioxide than the air we breathe in.
A diagram from Priestly’s letter: “Impregnating Water with Fixed Air”. Printed for J. Johnson, No. 72, in St. Pauls Church-Yard, 1772. (Click image for paper)
Back to Priestley for a moment. In the late 1800s, a glass of volcanic spring water was a common treatment for digestive problems and general ailments. But what if you didn’t happen to live near a volcanic spring? Joseph Black, you’ll remember, had established that CO2 was produced by living organisms, so it occurred to Priestly that perhaps he could hang a vessel of water over a fermentation vat at a brewery and collect the gas that way.
But it wasn’t very efficient. As Priestly himself said, “the surface of the fixed air is exposed to the common air, and is considerably mixed with it, [and] water will not imbibe so much of it by the process above described.”
It was then that he tried his experiment with vitriolic acid, which allowed for much greater control over the carbonation process. Priestly proposed that the resulting “water impregnated with fixed air” might have a number of medical applications. In particular, perhaps because the water had an acidic taste in a similar way that lemon-infused water does, he thought it might be an effective treatment for scurvy. Legend has it that he gave the method to Captain Cook for his second voyage to the Pacific for this reason. It wouldn’t have helped of course, but it does mean that Cook and his crew were some of the first people to produce carbonated water for the express purpose of drinking a fizzy drink.
You will have noticed that, despite all his work, there is no fizzy drink brand named Priestly (at least, not that I know of).
Joseph Priestley is credited with developing the first method for making carbonated water.
Today, carbonated drinks are made a little differently. You may have heard about carbon dioxide shortages this summer in the U.K. These arose because these days carbon dioxide is actually collected as a by-product of other processes. In fact, after several bits of quite simple chemistry that add up to a really elegant sequence.
From fertiliser to fizzy drinks
It all begins, or more accurately ends, with ammonia fertiliser. As any GCSE science student who’s been even half paying attention can tell you, ammonia is made by reacting hydrogen with nitrogen during the Haber process. Nitrogen is easy to get hold of – as I’ve already said it makes up nearly 80% of our atmosphere – but hydrogen has to be made from hydrocarbons. Usually natural gas, or methane.
This involves another well-known process, called steam reforming, in which steam is reacted with methane at high temperatures in the presence of a nickel catalyst. This produces carbon monoxide, a highly toxic gas. But no problem! React that carbon monoxide with more water in the presence of a slightly different catalyst and you get even more hydrogen. And some carbon dioxide.
Fear not, nothing is wasted here! The CO2 is captured and liquified for all sorts of food-related and industrial uses, not least of which is fizzy drinks. This works well for all concerned because steam reforming produces large amounts of pure carbon dioxide. If you’re going to add it to food and drinks after all, you wouldn’t want a product contaminated with other gases.
Carbon dioxide is a by-product of fertiliser manufacture.
We ended up with a problem this summer in the U.K. because ammonia production plants operate on a schedule which is linked to the planting season. Farmers don’t usually apply fertiliser in the summer – when they’re either harvesting or about to harvest crops – so many ammonia plants shut down for maintenance in April, May, and June. This naturally leads to reduction in the amount of available carbon dioxide, but it’s not normally a problem because the downtime is relatively short and enough is produced the rest of year to keep manufacturers supplied.
This year, though, natural-gas prices were higher, while the price of ammonia stayed roughly the same. This meant that ammonia plants were in no great hurry to reopen, and that meant many didn’t start supplying carbon dioxide in July, just when a huge heatwave hit the UK, coinciding with the World Cup football (which tends to generate a big demand for fizzy pop, for some reason).
Which brings us back to our atmosphere…
Carbon dioxide calamity?
Isn’t there, you may be thinking, too much carbon dioxide in our atmosphere? In fact, that heatwave you just mentioned, wasn’t that a global warming thing? Can’t we just… extract carbon dioxide from our air and solve everyone’s problems? Well, yes and no. Remember earlier when I said that at the beginning of the twentieth century and atmospheric carbon dioxide levels were about 300 ppm (0.03%)?
Over the last hundred years atmospheric carbon dioxide levels have increased from 0.03% to 0.04%
Today, a little over 100 years later, levels are about 0.04%. This is a significant increase in a relatively short period of time, but it’s still only a tiny fraction of our..
This is one of my favourite photos, so I’m using it again.
The school summer holidays are fast approaching and, for some reason, this always seems to get people talking about slime. Whether it’s because it’s a fun end-of-term activity, or it’s an easy bit of science for kids to do at home, or a bit of both, the summer months seem to love slimy stories. In fact, I wrote a piece about it myself in August 2017.
The article is illustrated with lots of pots of colourful commercial slime pots with equally colourful names like Jupiter Juice. It says that, “exposure to excessive levels of boron could cause irritation, diarrhoea, vomiting and cramps in the short term,” and goes on to talk about possible risks of birth defects and developmental delays. Yikes. Apparently the retailer Amazon has removed several slime toys from sale since Which? got on the case.
The piece was, as you might expect, picked up by practically every news outlet there is, and within hours the internet was full of headlines warning of the dire consequences of handling multicoloured gloopy stuff.
Before I go any further, here’s a quick reminder: most slime is made by taking polyvinyl alcohol (PVA – the white glue stuff) and adding a borax solution, aka sodium tetraborate, which contains the element boron. The sodium tetraborate forms cross-links between the PVA polymer chains, and as a result you get viscous, slimy slime in place of runny, gluey stuff. Check out this lovely graphic created by @compoundchem for c&en’s Periodic Graphics:
The Chemistry of Slime from cen.acs.org (click image for link), created by Andy Brunning of @compoundchem
And so, back to the Which? article. Is the alarm justified? Should you ban your child from ever going near slime ever again?
Nah. Followers will remember that back in August last year, after I posted my own slime piece, I had a chat with boron-specialist David Schubert. He said at the time: “Borax has been repeated[ly] shown to be safe for skin contact. Absorption through intact skin is lower than the B consumed in a healthy diet” (B is the chemical symbol for the element boron). And then he directed me to a research paper backing up his comments.
Borax is a fine white powder, Mixed with water it can be used to make slime.
This, by the way, is all referring to the chemical borax – which you might use if you’re making slime. In pre-made slime the borax has chemically bonded with the PVA, and that very probably makes it even safer – because it’s then even more difficult for any boron to be absorbed through skin.
Of course, and this really falls under the category of “things no one should have to say,” don’t eat slime. Don’t let your kids eat slime. Although even if they did, the risks are really small. As David said when we asked this time: “Borates have low acute toxicity. Consumption of the amount of borax present in a handful of slime would make one sick to their stomach and possibly cause vomiting, but no other harm would result. The only way [they] could harm themselves is by eating that amount daily.”
It is true that borax comes with a “reproductive hazard” warning label. Which? pointed out in their article that there is EU guidance on safe boron levels, and the permitted level in childrens’ toys has been set at 300 mg/kg (but when I looked, the only number I could find was the rather higher 1200 mg/kg – if anyone reading this can point me to the right link, please comment!).
This is a very cautious limit, based on animal studies, and not really representative of the actual hazards. Boron chemist Beth Bosley added more to the story, pointing out that while it is true that boric acid exposure has been shown to cause fetal abnormalities when it’s fed to pregnant rats, this finding hasn’t been reproduced in humans. Workers handling large quantities of borate in China and Turkey have been studied and no reproductive effects have been seen.
Rat studies, she pointed out, aren’t wholly comparable because rats are unable to vomit, which is significant because it means a rat can be fed a large quantity of a boron-containing substance and it’ll stay in their system. Whereas a human who accidentally ingested a similar dose would almost certainly throw up.
All that aside, we all let our children handle things that might be harmful if they ate them. Swallowing a whole tube of toothpaste would probably give your child an upset stomach, and it could even be dangerous if they did it on a regular basis, but we haven’t banned toothpaste “just in case”. We keep it out of reach when they’re not supposed to be brushing their teeth, and we teach them not to do silly things like eating an entire tube of Oral-B. Same basic principle applies to slime, even if it does turn out to contain more boron than the EU guidelines permit.
In conclusion: pots of pre-made slime are safe, certainly from a borax/boron point of view*, so long as you don’t eat them. The tiny amounts of boron that might be absorbed through skin are smaller than the amounts you’d get from eating nuts and pulses, and not at all hazardous.
Making slime at home can also be safe, if you follow some sensible guidelines like, say, these ones:
Stay safe with slime by following this guidance
Slime on, my chemistry-loving friends!
*I suppose it’s possible that someone could sell slime that’s contaminated with some other toxic thing. But that could happen with anything. The general advice to “wash your/their hands and don’t eat it” will take you a long way.