Spin Dynamics Phenomena of a Cerium(III) Double-Decker Complex Induced by Intramolecular Electron Transfer
RSC - Dalton Transaction Journal
by Keiichi Katoh, Kana Kobayashi, Michiyuki Suzuki, Tetsu Sato, Yoji Horii, Takefumi Yoshida, Brian. K. Breedlove, Masahiro Yamashita
5d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00436A, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Keiichi Katoh, Kana Kobayashi, Michiyuki Suzuki, Tetsu Sato, Yoji Horii, Takefumi Yoshida, Brian. K. Breedlove, Masahiro Yamashita Switchable spin dynamic properties in single-molecule magnets (SMMs) via an applied stimulus have applications in single-molecule devices. Many SMMs containing heavy lanthanoid ions with strong uniaxial magnetic anisotropy have been... The content of this RSS Feed (c) The Royal Society of ..read more
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Investigation of Ln3+ complexation by a DOTA derivative substituted by an imidazothiadiazole: synthesis, solution structure, luminescence and relaxation properties
RSC - Dalton Transaction Journal
by Emma Caillet, Léa Nunes, Svetlana Valer'evna Eliseeva, Modou Ndiaye, Manon Isaac, Agnes Pallier, Jean-François Morfin, Hervé Meudal, Stephane Petoud, Sylvain Routier, Carlos Platas-Iglesias, Frédéric Buron, Célia S. Bonnet
5d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00533C, Paper Emma Caillet, Léa Nunes, Svetlana Valer'evna Eliseeva, Modou Ndiaye, Manon Isaac, Agnes Pallier, Jean-François Morfin, Hervé Meudal, Stephane Petoud, Sylvain Routier, Carlos Platas-Iglesias, Frédéric Buron, Célia S. Bonnet We investigated the coordination properties of original macrocyclic Ln3+ complexes comprising an imidazothiadiazole heterocycle. The thermodynamic stability of the Gd3+ complex was determined by a combination of potentiometric and photophysical... The content of this RSS Feed (c) The Royal Society of Che ..read more
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Organometallics in Molecular Junctions: Conductance, Functions, and Reactions
RSC - Dalton Transaction Journal
by Yuya Tanaka
5d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00668B, Perspective Yuya Tanaka Molecular junctions, which involve sandwiching molecular structures between electrodes, play a crucial role in molecular electronics. Recent advances in this field have revealed the vital role of organometallic chemistry in... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Layered rare-earth hydroxides as multi-modal medical imaging probes: particle size optimisation and compositional exploration
RSC - Dalton Transaction Journal
by Margarita Strimaite, Connor J. R. Wells, Timothy J. Prior, Daniel James Stuckey, Jack Wells, Gemma-Louise Davies, Gareth R Williams
5d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00371C, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Margarita Strimaite, Connor J. R. Wells, Timothy J. Prior, Daniel James Stuckey, Jack Wells, Gemma-Louise Davies, Gareth R Williams Recently, layered rare-earth hydroxides (LRHs) have received growing attention in the field of theranostics. We have previously reported the hydrothermal synthesis of layered terbium hydroxide (LTbH), which exhibited high biocompatibility,... The content of this RSS Feed (c) The Royal Soc ..read more
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Highly Cytotoxic Cu(II) Terpyridine Complexes as Chemotherapeutic Agents
RSC - Dalton Transaction Journal
by Kaixin Ni, Nicolás Montesdeoca, Johannes Karges
5d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00759J, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Kaixin Ni, Nicolás Montesdeoca, Johannes Karges Cancer is considered as the biggest medicinal challenge worldwide. During a typical treatment, the tumorous tissue is removed in a surgical procedure and the patient further treated by chemotherapy. One... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Reactivity of Schiff base-[C,N,S] pincer palladacycles: hydrolysis renders singular trinuclear, tetranuclear, and heteropentanuclear Pd3W2 coordinated complexes
RSC - Dalton Transaction Journal
by Jose M. Vila, Francisco Reigosa, M. Teresa Pereira, Paula M. Polo
5d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00756E, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Jose M. Vila, Francisco Reigosa, M. Teresa Pereira, Paula M. Polo Treatment of the Schiff base ligands a-f with Li2[PdCl4] / NaAcO in methanol under reflux gave the single nuclear palladacycles 1a-1f, with the metal atom bonded to a terdentate monoanionic... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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An innovative synthesis of carbon-coated TiO2 nanoparticles as host for Na+ intercalation for sodium-ion batteries
RSC - Dalton Transaction Journal
by Tanguy SOUDANT, Solenne Fleutot, Stéphanie Bruyère, Lucie Speyer, Sébastien Hupont, Mickaël Bolmont, Thomas Girardet, Loris Raspado, Claire Hérold, Sébastien Cahen
5d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00459K, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Tanguy SOUDANT, Solenne Fleutot, Stéphanie Bruyère, Lucie Speyer, Sébastien Hupont, Mickaël Bolmont, Thomas Girardet, Loris Raspado, Claire Hérold, Sébastien Cahen In this work, an innovative route to synthesize anatase TiO2@C composite is presented. The synthesis was conducted by a soft chemistry microwave-assisted method using titanium(IV) butoxide as titanium precursor. The... The content of this RSS ..read more
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Computational design of cooperatively acting molecular catalyst systems: carbene based tungsten- or molybdenum-catalysts with rhodium- or iridium-complexes for the ionic hydrogenation of N2 to NH3
RSC - Dalton Transaction Journal
by Totan Mondal, Walter Leitner, Markus Hölscher
5d ago
Dalton Trans., 2024, Advance Article DOI: 10.1039/D4DT00563E, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Totan Mondal, Walter Leitner, Markus Hölscher Low activation barriers allow for NH3 synthesis from N2/H2 using cooperatively acting catalysts based on carbene pincer complexes. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Theoretical exploration of the nitrogen fixation mechanism of two−dimensional dual−metal FeTM@GY (TM = Fe, Mo, Co, and V) electrocatalysts
RSC - Dalton Transaction Journal
by Lin Yuan, Qinglong Fang, Baiyu Zhang
6d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT04384C, Paper Lin Yuan, Qinglong Fang, Baiyu Zhang In contrast to the energy-consuming Haber-Bosch process, ammonia synthesis by electrocatalysis under ambient conditions is an efficient and environmentally friendly method. In this work, through first principles calculations, the potential... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Plastic Phase Transitions in Tris(hydroxymethyl)aminomethane Perchlorate
RSC - Dalton Transaction Journal
by Feng Zhou, Yan-Ran Weng, Yu Shi, Yun-Hui Yu, dan lu, yong yu, jiazi she, Yong Ai
6d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00791C, Paper Feng Zhou, Yan-Ran Weng, Yu Shi, Yun-Hui Yu, dan lu, yong yu, jiazi she, Yong Ai Organic crystal materials with metal-free feature and intrinsically low molecular mass are highly desirable for applications in flexible smart devices. Here, we reported a plastic crystal, tris(hydroxymethyl)aminomethane perchlorate (Tris-HClO4), which... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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