Theoretical exploration of the nitrogen fixation mechanism of two−dimensional dual−metal FeTM@GY (TM = Fe, Mo, Co, and V) electrocatalysts
RSC - Dalton Transaction Journal
by Lin Yuan, Qinglong Fang, Baiyu Zhang
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D3DT04384C, Paper Lin Yuan, Qinglong Fang, Baiyu Zhang In contrast to the energy-consuming Haber-Bosch process, ammonia synthesis by electrocatalysis under ambient conditions is an efficient and environmentally friendly method. In this work, through first principles calculations, the potential... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Plastic Phase Transitions in Tris(hydroxymethyl)aminomethane Perchlorate
RSC - Dalton Transaction Journal
by Feng Zhou, Yan-Ran Weng, Yu Shi, Yun-Hui Yu, dan lu, yong yu, jiazi she, Yong Ai
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00791C, Paper Feng Zhou, Yan-Ran Weng, Yu Shi, Yun-Hui Yu, dan lu, yong yu, jiazi she, Yong Ai Organic crystal materials with metal-free feature and intrinsically low molecular mass are highly desirable for applications in flexible smart devices. Here, we reported a plastic crystal, tris(hydroxymethyl)aminomethane perchlorate (Tris-HClO4), which... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Synthesis of tricyclic 1,4-dihydro-1,4-phosphagermines - trying to establish molecular fencing of reactive centers
RSC - Dalton Transaction Journal
by Mridhul Ramachandran, Surendar Karwasara, Hui Zhu, Gregor Schnakenburg, R. Streubel
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00895B, Paper Mridhul Ramachandran, Surendar Karwasara, Hui Zhu, Gregor Schnakenburg, R. Streubel Novel tricyclic 1,4-dihydro-1,4-phosphagermines (3a and 4a) were synthesised from bis(1,3-imidazole-2-thione)-substituted difunctional germane derivative 2a; all structures were crystallographically confirmed. In going from rather small alkyl substituents (Me, nBu) at the... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Bidentate Boron Lewis Acids: Synthesis by Tin Boron Exchange Reaction and Host-Guest Complex Formation
RSC - Dalton Transaction Journal
by Jean Louis Beckmann, Beate Neumann, Georg Stammler, Jan-Hendrik Lamm, Norbert Werner Mitzel
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00782D, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Jean Louis Beckmann, Beate Neumann, Georg Stammler, Jan-Hendrik Lamm, Norbert Werner Mitzel Four bidentate boron Lewis acids based on the 1,8-diethynylanthracene backbone have been synthesized by a tin-boron exchange reaction with various chloroboranes, yielding the products in good to excellent yields. Complexation... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Origin of the Cr3+ concentration-dependent broadband near-infrared emission in Sc2Si2O7
RSC - Dalton Transaction Journal
by Siyuan Xie, Boxin Ma, Dawei Wen, Qingguang Zeng, Yue Guo, Ting Yu
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00784K, Communication Siyuan Xie, Boxin Ma, Dawei Wen, Qingguang Zeng, Yue Guo, Ting Yu The challenge of developing phosphors with tailored near-infrared (NIR) emission ranges to meet the diverse demands of various applications is a paramount concern in the contemporary realm of NIR phosphor... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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A Detailed Density Functional Theory Exploration of the Photodissociation Mechanism of Ruthenium Complexes for Photoactivated Chemotherapy
RSC - Dalton Transaction Journal
by Daniele Belletto, Fortuna Ponte, Gloria Mazzone, Emilia Sicilia
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00834K, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Daniele Belletto, Fortuna Ponte, Gloria Mazzone, Emilia Sicilia Polypyridyl Ru(II) complexes have attracted much attention due to their potential as light-activatable anticancer agents to be used in Photoactivated chemotherapy (PACT). The action of ruthenium-based PACT compounds relies on... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Polymorph transformation in a mixed-stacking nickel-dithiolene complex with the derivative of 4,4'-bipyridinium
RSC - Dalton Transaction Journal
by Yan Gao, Lei Xu, Zi-Heng Feng, yin Qian, Zhengfang Tian, Xiaoming Ren
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00324A, Paper Yan Gao, Lei Xu, Zi-Heng Feng, yin Qian, Zhengfang Tian, Xiaoming Ren In this study, two polymorphs of [1,1′-dibutyl-4,4′-bipyridinium][Ni(mnt)2] salt were synthesized. The dark-green polymorph (designated as 1-g) was prepared under ambient conditions by rapid precipitation method in aqueous solutions. Subsequently, the... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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Dinuclear NHC-gold(I)-thiolato and -alkynyl complexes: synthesis, anticancer activity, and catalytic activity in lactonization reactions
RSC - Dalton Transaction Journal
by Steven P Nolan, Xinyuan Ma, yuan zhao, Isabella Caligiuri, Flavio Rizzolio, Nestor Bracho, Kristof Van Hecke, Thomas Scattolin
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00890A, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Steven P Nolan, Xinyuan Ma, yuan zhao, Isabella Caligiuri, Flavio Rizzolio, Nestor Bracho, Kristof Van Hecke, Thomas Scattolin A series of novel dinuclear NHC-gold-thiolato and -alkynyl complexes bearing aromatic linkers were successfully synthesized by an efficient and simple synthetic route. The catalytic activity of these complexes waas tested... The content of this RSS Feed (c) The Royal Society of C ..read more
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Unveiling the promising anticancer activity of palladium(II)-aryl complexes bearing diphosphine ligands: a structure-activity relationship analysis
RSC - Dalton Transaction Journal
by Giovanni Tonon, Matteo Mauceri, Enrico Cavarzerani, Rachele Piccolo, Claudio Santo, Nicola Demitri, Laura Orian, Pablo Andrei Nogara, Joao Batista Teixeira Rocha, Vincenzo Canzonieri, Flavio Rizzolio, Fabiano Visentin, Thomas Scattolin
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00919C, Paper Open Access &nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Giovanni Tonon, Matteo Mauceri, Enrico Cavarzerani, Rachele Piccolo, Claudio Santo, Nicola Demitri, Laura Orian, Pablo Andrei Nogara, Joao Batista Teixeira Rocha, Vincenzo Canzonieri, Flavio Rizzolio, Fabiano Visentin, Thomas Scattolin In continuation with our previous works on cytotoxic properties of organopalladium compounds, in this contribution we described the first systematic study of the anticancer activity of ..read more
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The effect of light irradiation on nitro-ruthenium porphyrin complex in the induced death of lung cancer cells in two- and three-dimensional cultures: Insights into the effect of nitric oxide
RSC - Dalton Transaction Journal
by Roberto Santana da Silva, Amanda Becceneri, Matheus Martin, Angélica E. Graminha, Marcia Regina Cominetti, Peter C Ford
1d ago
Dalton Trans., 2024, Accepted Manuscript DOI: 10.1039/D4DT00381K, Paper Roberto Santana da Silva, Amanda Becceneri, Matheus Martin, Angélica E. Graminha, Marcia Regina Cominetti, Peter C Ford Efforts to find compounds selectively affecting cancer cells while sparing normal ones have continued to grow. Nitric oxide (NO) is critical in physiology and pathology, including cancer. It influences cellular... The content of this RSS Feed (c) The Royal Society of Chemistry ..read more
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